Constructing Ionic Transport Network via Supramolecular Composite Binder in Cathode for All‐Solid‐State Lithium Batteries

-based ASSLBs show an excellent rate capability and long cyclic stability over 1000 cycles at 1 C. Notably, a pouch ASSLB shows excellent cycling stability over 250 cycles at 0.2 C. This work provides guidance on designing high-loading cathodes for advanced ASSLBs.