A strategy to fabricate hierarchical microporous architecture of polyimide nanofibrous aerogels with efficient electromagnetic wave absorption and thermal insulation

The aviation industry requires advanced aerogels that combine both electromagnetic wave (EM) attenuation and thermal insulation capabilities. This work involved the fabrication of Ti3C2Tx MXene/polyimide nanofibrous (PINF) aerogels through freeze-drying and thermal imidization. The hierarchical microporous architecture was formed by the interconnected primary pores induced by the removal of ice crystals and secondary pores from the PINF web. The unique highly porous 3D network of the nanofibrous aerogel provided well-matched impedance and enhanced multiple reflections and scattering of EM waves. The polar functional groups and defects on MXene induced dipole polarization, and the heterointerfaces between the PINFs and MXene enhanced the interfacial polarization. Consequently, the MXene/PINF aerogels exhibited efficient microwave absorption, showing a minimum reflection loss (RLmin) of −37.9 dB and an effective absorption bandwidth (EAB) of 3.3 GHz. Moreover, nanofibrous aerogels also exhibited low thermal conductivity and remarkable compression properties, making them suitable for utilization in complex environments.