超级电容器
材料科学
电化学
电容
电解质
功率密度
储能
化学工程
电流密度
电极
纳米技术
多孔性
复合材料
功率(物理)
化学
量子力学
物理
工程类
物理化学
作者
Atefeh Sharifi,Majid Arvand,Samaneh Daneshvar
标识
DOI:10.1016/j.jallcom.2020.158101
摘要
Wire-shaped supercapacitors, a new class of energy storage devices, have recently received enormous attention advantages of miniature size, lightweight and high flexibility. However, most of the reported wire-shaped supercapacitors are still suffered from low specific capacitance and limited energy densities as well as the relatively poor electrochemical performance. In this research, Co(OH)2@Ni(OH)2 nanosheets were successfully synthesized on the 3D-Ni film-coated Ni wire (NW) by electrochemical methods. The electrochemical tests of Co(OH)2@Ni(OH)2/3D-Ni/NW electrode confirmed the outstanding supercapacitive behavior of nanostructures with excellent cycling stability. This behavior could be attributed to 3D network structure of Ni film and the nanosheets which allow facile electrolyte and electrons transportation. Detailed electrochemical characterization shows that the Co(OH)2@Ni(OH)2/3D-Ni/NW exhibits a high specific capacitance of 355.2 C g–1 at current density of 1 Ag–1 and excellent cycle performance (80.0% retention after 3000 CD cycles). Also, the maximum energy density of 27.24 W h kg–1 at the power density of 234.99 W kg–1 was measured. The obtained results reveal that the Co(OH)2@Ni(OH)2 core-shell can be a promising electroactive material for supercapacitors. This unique supercapacitor opens up a new path in the development of fiber-shaped energy storage apparatuses.
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