化学
催化作用
金属有机骨架
异质结
纳米颗粒
化学工程
吸附
纳米材料基催化剂
纳米技术
金属
无机化学
材料科学
物理化学
有机化学
光电子学
工程类
作者
Xi Chen,Yanshuang Zhang,Yutao Zhao,Shan Wang,Lingzhi Liu,Wenyuan Xu,Zanru Guo,Shaohui Wang,Yongxin Liu,Jiali Zhang
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2019-09-06
卷期号:58 (18): 12433-12440
被引量:38
标识
DOI:10.1021/acs.inorgchem.9b02114
摘要
Metal–organic framework (MOF)-based magnetic Pt catalyst Fe3O4@Pt@MIL-100(Fe) core–shell heterostructures were prepared through transforming Fe3O4 into MIL-100(Fe) in benzene-1,3,5-tricarboxylic acid solution along with encapsulating the Pt nanoparticles successively adsorbed onto the surface of the Fe3O4 nanosphere and the continuously forming surfaces of the growing MIL-100(Fe) crystals. This method circumvented the obstacles, controlling the formation of metal nanoparticles (MNPs) inside MOFs or regulating growth of MOFs around the MNPs, for preparing an MNP–MOF composite catalyst. The obtained well-defined Fe3O4@Pt@MIL-100(Fe) core–shell heterostructure was shown promoting catalytic activity on the reduction of 4-nitrophenol due to the synergistic effect between the Pt nanoparticles and the MIL-100(Fe) shell and recycling convenience due to the rapid separation of the Fe3O4 core under an external magnetic field.
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