超级电容器
重量分析
阳极
双金属片
材料科学
储能
功率密度
电极
阴极
电化学
纳米材料
化学工程
能量密度
电容
纳米颗粒
纳米技术
化学
冶金
功率(物理)
工程物理
物理
工程类
量子力学
物理化学
有机化学
金属
作者
Khem Raj Shrestha,Syam Kandula,Nam Hoon Kim,Joong Hee Lee
标识
DOI:10.1016/j.cej.2020.127046
摘要
A supercapacitor would be one of the most reliable energy storage device, but due to inadequate energy density, it is restricted to commercialization. The bimetallic core nanoparticles possess multiple oxidation states in their [email protected] design, and understanding the effect of tuning of core cations are noble artifacts for effective research. Here, an effective strategy of varying the cations (M = Ni, Zn and Mn) in the MxCo3-xS4@NiMoS4 [email protected] is demonstrated. Among the MxCo3-xS4@NiMoS4 electrodes, the NiCo2S4@NiMoS4 [email protected] showed better electrochemical storage properties with areal capacity/gravimetric capacity of 0.92 mAh cm−2/287.5 mAh g−1 at 3 mA cm−2 (3410.0 F g−1 capacitance), and superior cycle life with ca. 92.3% capacity retention at high current density of 50.0 mA cm−2 after 10,000 cycles. Moreover, real–time application was monitored by assembling an asymmetric solid–state device, taking NiCo2S4@NiMoS4 as the cathode and Fe2O3/NG hydrogel as the anode. The device delivers an excellent cell capacity of 90.4 mA hg−1 with a remarkable cycle life of 90.5% after 10,000 cycles. The device stored a very high energy density of 72.3 Wh kg–1at 460.0 W kg−1 and retained an energy density of 32.6 Wh kg−1 at a high power density of 11,844.0 W kg−1, demonstrating high applicability towards practical energy storage devices.
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