电解质
阴极
阳极
化学工程
锂(药物)
材料科学
相间
电池(电)
比能量
金属
金属锂
能量密度
化学
冶金
电极
工程物理
热力学
物理
工程类
内分泌学
物理化学
功率(物理)
生物
医学
遗传学
作者
Xueqiang Zhang,Tao Li,Bo‐Quan Li,Rui Zhang,Peng Shi,Chong Yan,Jia‐Qi Huang,Qiang Zhang
标识
DOI:10.1002/anie.201911724
摘要
High-energy-density Li metal batteries suffer from a short lifespan under practical conditions, such as limited lithium, high loading cathode, and lean electrolytes, owing to the absence of appropriate solid electrolyte interphase (SEI). Herein, a sustainable SEI was designed rationally by combining fluorinated co-solvents with sustained-release additives for practical challenges. The intrinsic uniformity of SEI and the constant supplements of building blocks of SEI jointly afford to sustainable SEI. Specific spatial distributions and abundant heterogeneous grain boundaries of LiF, LiNx Oy , and Li2 O effectively regulate uniformity of Li deposition. In a Li metal battery with an ultrathin Li anode (33 μm), a high-loading LiNi0.5 Co0.2 Mn0.3 O2 cathode (4.4 mAh cm-2 ), and lean electrolytes (6.1 g Ah-1 ), 83 % of initial capacity retains after 150 cycles. A pouch cell (3.5 Ah) demonstrated a specific energy of 340 Wh kg-1 for 60 cycles with lean electrolytes (2.3 g Ah-1 ).
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