溶解有机碳
环境化学
吸附
化学
生物利用度
降级(电信)
有机质
解吸
土壤水分
环境科学
土壤科学
有机化学
电信
生物信息学
计算机科学
生物
作者
Yuwen Qi,Huimin Cao,Wei Pan,Cuiping Wang,Yanna Liang
标识
DOI:10.1016/j.jhazmat.2022.129139
摘要
The negative effects of polyfluoroalkyl substances (PFAS) on the environment and health have recently attracted much attention. This article reviews the influence of soil- and water-derived dissolved organic matter (DOM) on the environmental fate of PFAS. In addition to being co-adsorped with PFAS to increase the adsorption capacity, DOM competes with PFAS for adsorption sites on the surface of the material, thereby reducing the removal rate of PFAS or increasing water solubility, which facilitates desorption of PFAS in the soil. It can quench some active species and inhibit the degradation of PFAS. In contrast, before DOM in water self-degrades, DOM has a greater promoting effect on the degradation of PFAS because DOM can complex with iron, iodine, among others, and act as an electron shuttle to enhance electron transfer. In soil aggregates, DOM can prevent microorganisms from being poisoned by direct exposure to PFAS. In addition, DOM increases the desorption of PFAS in plant root soil, affecting its bioavailability. In general, DOM plays a bidirectional role in adsorption, degradation, and plant uptake of PFAS, which depends on the types and functional groups of DOM. It is necessary to enhance the positive role of DOM in reducing the environmental risks posed by PFAS. In future, attention should be paid to the DOM-induced reduction of PFAS and development of a green and efficient continuous defluorination technology.
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