材料科学
聚酯纤维
极限抗拉强度
缩聚物
玻璃化转变
热分解
无定形固体
延展性(地球科学)
复合材料
聚乳酸
耐化学性
高分子化学
化学工程
聚合物
有机化学
化学
蠕动
工程类
作者
Ang Shen,Jinggang Wang,Xiaoqin Zhang,Fu‐Zhen Xuan,Lin Fan,Yanliu Zhu,Yunxiao Dong,Jin Zhu
摘要
Abstract The polyesters with high T g (≥100°C) and good clarity are desired in fabricating heat‐resistance containers such as baby bottles, cups, medical apparatus, and kitchen appliances. In this work, a series of poly(butylene bis[4‐(2‐hydroxyethoxy) phenyl] sulfone 1,4‐cyclohexanedimethylene 2,5‐furandicarboxylate) (PBSCFs) that show superior thermal and mechanical properties against current bio‐based polyesters were synthesized via a melt polycondensation method. The accurate chemical structures of PBSCFs were confirmed by 1 H‐NMR and 13 C‐NMR. The SEC results show that PBSCFs have number averaged molar mass ( M n ) in the range of 9700–28,500 g/mol. The T g of PBSCFs increase from 94°C for PBSF to 108°C for PBSCF‐50 as the increasing of CHDM unit. Meanwhile, the ductility of PBSCFs also improved with the elongation at break of PBSCF‐40 increased to 223%. In addition, the PBSCF‐40 sample reported in this paper shows thermal decomposition temperature of 427°C, transmittance of 84.6%, haze of only 0.17%, tensile strength of 74.1 MPa, and tensile modulus of 2287 MPa.
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