化学
环丙烯
脱卤化氢
戒指(化学)
亲核细胞
亲核加成
亲核取代
药物化学
组合化学
立体化学
有机化学
催化作用
作者
Andrew R. Edwards,Marina Rubina,Michael Rubin
标识
DOI:10.2174/1385272820666160331235409
摘要
This review encompasses addition reactions of cyclopropenes proceeding with retention of the small ring as well as cascade transformations involving ring-opening. Formal nucleophilic substitution of halocyclopropanes operating via a dehydrohalogenation-addition mechanism with the formation of cyclopropene intermediates is also discussed. Relevant literature published in the period of 2005-2015 is surveyed. Keywords: Cyclopropanes, cyclopropenes, nucleophilic addition, nucleophiles, strain release.
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