Broadband and wide-angle antireflective subwavelength microstructures on zinc sulfide fabricated by femtosecond laser parallel multi-beam

The subwavelength microstructures (SWMS) on the surface of ZnS for antireflection in an infrared band have been theoretically designed and experimentally fabricated. The finite difference time domain (FDTD) simulation has been utilized to optimize geometry for obtaining high transmittance of SWMS. Then, during simulation for light field intensity distribution, the inner of SWMS emerges location and wavelength dependent light resonant region, which can be explained by Wood-Rayleigh (WR) law. Furthermore, according to refractive index gradient formation and light field coupling effect, the grating period and height are capable of regulating the band selection of antireflection and value of the transmittance, respectively. In addition, a rapid facile approach based on femtosecond laser parallel multi-beam has been proposed to experimentally realize the designed and optimal structures. The depth, period, and embedded nano-gratings of fabricated SWMS are tunable by controlling laser-processing parameters for antireflection in the wavelength of 8 μm-12 μm. Finally, the broadband and wide-angle antireflective SWMS on ZnS as well as robust mechanical strength and hydrophobicity have been achieved, expecting to be of great potential in an optoelectronic device application.