催化作用
溶剂
金属
化学
相(物质)
动力学
氢
溶剂效应
化学动力学
反应速率
微晶
液相
传质
有机化学
热力学
色谱法
物理
量子力学
结晶学
作者
Utpal Singh,M. A. Vannice
标识
DOI:10.1016/s0926-860x(00)00885-1
摘要
The kinetics of liquid-phase hydrogenation reactions have been reviewed with a special emphasis on α, β-unsaturated aldehydes as reactants. These reactions can be complex and can be influenced by factors such as metal specificity, side reactions, and metal-support interactions as well as reaction parameters. The importance of results in the absence of heat and mass transfer limitations has been emphasized. Hydrogenation reactions are typically assumed to be structure-sensitive, but dependencies on metal crystallite size have been reported; however, this behavior has been attributed to side reactions which can inhibit activity. Finally, solvent effects can exist, but the effect of H2 concentration in the liquid phase has infrequently been isolated. Thermodynamic arguments indicate that a solvent effect can enhance the surface coverage of hydrogen on the catalyst surface at a constant H2 partial pressure, but in the absence of any solvent effects, surface coverage is independent of the liquid-phase H2 concentration.
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