材料科学
电解质
计算流体力学
质子交换膜燃料电池
工作(物理)
有限元法
传热
膜
压力(语言学)
电极
对流
扩散
膜电极组件
复合材料
机械
机械工程
热力学
结构工程
化学
工程类
物理
生物化学
哲学
物理化学
语言学
作者
Carlos Martinez-Baca,Rowland P. Travis
标识
DOI:10.1115/fuelcell2004-2469
摘要
The aim of this work is to determine the relationship between the operational characteristics of a Polymer Electrolyte Membrane (PEM) fuel cell, and the relevant materials issues and in particular mechanical stresses that develop. A three dimensional, non-isothernal, single phase model of a single channel PEM fuel cell is developed to investigate the impact of temperature variation on the Membrane Electrode Assembly (MEA). The model accounts for heat transfer in solids as well as in the multi-component mixture of gases, convection and diffusion of different species in the porous electrodes and the channels, electrochemical reactions and transport of water and ions through the PEM. This model has been numerically implemented in a commercial Computational Fluid Dynamic (CFD), finite volume based code. Temperature contours derived from the model were then exported to a commercial Finite Element (FE) code to analyse the relevant mechanical issues of the PEM and in particular thermomechanical stresses that develop. Initial results verify that, even considering the polymer electrolyte membrane in isolation with mechanically free boundary conditions, there is a significant temperature difference leading to tensile stresses of up to 2.1 MPa within the membrane.
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