How About Vanadium‐Based Compounds as Cathode Materials for Aqueous Zinc Ion Batteries?

Aqueous zinc-ion batteries (AZIBs) stand out among many monovalent/multivalent metal-ion batteries as promising new energy storage devices because of their good safety, low cost, and environmental friendliness. Nevertheless, there are still many great challenges to exploring new-type cathode materials that are suitable for Zn²⁺ intercalation. Vanadium-based compounds with various structures, large layer spacing, and different oxidation states are considered suitable cathode candidates for AZIBs. Herein, the research advances in vanadium-based compounds in recent years are systematically reviewed. The preparation methods, crystal structures, electrochemical performances, and energy storage mechanisms of vanadium-based compounds (e.g., vanadium phosphates, vanadium oxides, vanadates, vanadium sulfides, and vanadium nitrides) are mainly introduced. Finally, the limitations and development prospects of vanadium-based compounds are pointed out. Vanadium-based compounds as cathode materials for AZIBs are hoped to flourish in the coming years and attract more and more researchers' attention.