Boosting the Efficiency of Perovskite/Organic Tandem Solar Cells via Enhanced Near‐Infrared Absorption and Minimized Energy Losses

Abstract The compatibility of perovskite and organic photovoltaic materials in solution processing provides a significant advantage in the fabrication of high‐efficiency perovskite/organic tandem solar cells. However, additional recombination losses can occur during exciton dissociation in organic materials, leading to energy losses in the near‐infrared region of tandem devices. Consequently, a ternary organic rear subcell is designed containing two narrow‐bandgap non‐fullerene acceptors to enhance the absorption of near‐infrared light. Simultaneously, a unique diffusion‐controlled growth technique is adopted to optimize the morphology of the ternary active layer, thereby improving exciton dissociation efficiency. This innovation not only broadens the absorption range of near‐infrared light but also facilitates the generation and effective dissociation of excitons. Owing to these technological improvements, the power conversion efficiency (PCE) of organic solar cells increased to 19.2%. Furthermore, a wide‐bandgap perovskite front subcell is integrated with a narrow‐bandgap organic rear subcell to develop a perovskite/organic tandem solar cell. Owing to the reduction in near‐infrared energy loss, the PCE of this tandem device significantly improved, reaching 24.5%.