Reinforced Magnetic‐Responsive Electro‐Ionic Artificial Muscles by 3D Laser‐Induced Graphene Nano‐Heterostructures

Abstract Efficient ion transport and enriched responsive modals via modulating electrochemical properties of conductivity and capacitance are essential for soft electro‐ionic actuators. However, cost‐effective and straightforward approaches to achieve expedited fabrication of active electrode materials capable of multimodal‐responsiveness remain limited. Herein, this work reports the one‐step ultrafast laser direct patterning method, to readily synthesize electro‐ and magneto‐active electrode material, derived from the unique cobalt‐phosphorus co‐doped core–shell heterostructures within 3D graphene frameworks, for fulfilling the dual‐mode responsive electro‐ionic actuators. The designed nanofiber‐structured heterointerfaces across electrodes and electrolytes further promote highly efficient electron/ion transfer. The developed soft actuator exhibits superior actuation performance of peak‐to‐peak displacement to 13.08 mm under an ultra‐low ±0.5 V, with doubled direct current deflection under 200 mT at 1 V, an ultrafast response of 1.38 s and long‐term stability (>90% retention for ≈106 000 cycles), even detectable bending to ≈280 µm under exceptional ±10 mV. The promising demonstration of promoting differentiation and proliferation of stem cells under mechanical strain and electrical stimuli, sheds more light as well on the possibility of facilitating biomedical soft robotics with ultrahigh actuation performance.