Chiroptical Switching of Electrochromic Polymer Thin Films

Abstract The interaction between light and chiroptical polymers plays a crucial role in chiroptics, spintronics, and chiral‐spin selectivity. Despite considerable successes in creating dissymmetric polymer films, the elucidation of chiroptical activities under electrochemical switching remains unexplored. Here homogeneous chiral electrochromics is reported using chiral assembly of conjugated polymers through a transient solidification process with molecular chiral templates. In their neutral state, the chiral electrochromic polymers directly produce a remarkably dissymmetric polarization‐dependent transmittance. The circular dichroism (CD) and dissymmetric transmission can be tuned by adjusting the doping level of the electrochemically active polymer films. Under high levels of oxidation, the chiroptical activities are reversed with strong bleaching in the visible, leading to formation of monosignate CD spectra over the infrared region. The matching between circular polarization handedness and chirality of chiroptical polymers makes a distinct impact on optical contrast and color switching dynamics due to the flipped chiroptical activities through polymer redox reactions. The differential circularly polarized transmission in the chiral see‐through display can make a well‐resolved color change in human eyes, demonstrating proof‐of‐concept devices for 3D imaging and information encryption. This work serves as a foundation to develop advanced on‐chip fabrication of circular polarization‐multiplexed display in flexible and highly integrated platforms.