Breaking the Barrier: Strategies for Mitigating Shuttle Effect in Lithium–Sulfur Batteries Using Advanced Separators

Lithium-sulfur (Li-S) batteries are considered one of the most promising energy storage systems due to their high theoretical capacity, high theoretical capacity density, and low cost. However, challenges such as poor conductivity of sulfur (S) elements in active materials, the "shuttle effect" caused by lithium polysulfide, and the growth of lithium dendrites impede the commercial development of Li-S batteries. As a crucial component of the battery, the separator plays a vital role in mitigating the shuttle effect caused by polysulfide. Traditional polypropylene, polyethylene, and polyimide separators are constrained by their inherent limitations, rendering them unsuitable for direct application in lithium-sulfur batteries. Therefore, there is an urgent need for the development of novel separators. This review summarizes the applications of different separator preparation methods and separator modification methods in lithium-sulfur batteries and analyzes their electrochemical performance.