Single–atom catalysts based on Fenton-like/peroxymonosulfate system for water purification: design and synthesis principle, performance regulation and catalytic mechanism

), and persulfate (PSs)) to release active radicals and non-radicals, acting on target pollutants, and realize their decomposition and mineralization. Among them, peroxymonosulfate (PMS) in PS systems has gradually become an important oxidant in Fenton-like processes due to its asymmetric molecular structure and characteristics of easy storage and transportation. Focusing on the numerous proposed strategies for the synthesis and performance regulation of Fenton-like SACs, it has been confirmed that the coordination of isolated metal atoms and the support/carrier enhances the structural robustness and chemical stability of these catalysts and optimizes their catalytic activity and kinetics. Moreover, the tunability of the coordination environment and electronic properties of SACs can improve their other catalytic properties, such as cycle stability and selectivity. Thus, to systematically explain the relationship between the active center, catalyst performance and the corresponding potential catalytic mechanism, herein, we focus on the representative scientific work on the preparation strategy, catalytic application and performance regulation of Fenton-like SACs. Specifically, we review the typical Fenton-like SAC reaction processes and catalytic mechanisms for the degradation of refractory organic compounds in advanced oxidation processes (AOPs). Finally, the future development and challenges of Fenton-like SACs are presented.