有机催化
化学
卤键
催化作用
卤素
超分子化学
单独一对
有机化学
氢键催化
氢键
非共价相互作用
组合化学
分子
对映选择合成
烷基
作者
Ying Li,Chang Zhao,Zhuo Wang,Yanli Zeng
标识
DOI:10.1021/acs.jpca.3c06363
摘要
As important noncovalent interactions, halogen bonds have been widely used in material science, supramolecular chemistry, medicinal chemistry, organocatalysis, and other fields. In the past 15 years, halogen bond catalysis has become a developed field in organocatalysis for the catalysts' advantages of being environmentally friendly, inexpensive, and recyclable. Halogen bonds can induce various organic reactions, and halogen bond catalysis has become a powerful alternative to the fully explored hydrogen bond catalysis. From a physical chemistry view, this perspective provides an overview of the latest progress and key examples of halogen bond catalysis via activation of the lone pair systems of organic functional group, π systems, and metal complexes. The research progresses in halogen bond catalysis by our group were also introduced.
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