Mixed-valent cobalt phosphate/borophene nanohybrids for efficient electrocatalytic oxygen evolution reaction

Developing efficient, low-cost, non-precious and stable electrocatalyst is necessary for sustainable electrocatalytic water splitting. Recently, borophene has emerged as a novel two-dimensional material with exciting properties. Although several researchers have theoretically predicted its applicability towards effective electrocatalytic water splitting, studies on its practical applications are still limited. In this regard, a mixed-valent cobalt phosphate/borophene nanohybrid (BCoPi) was synthesized using hydrothermal method, and its activity towards oxygen evolution reaction (OER) was systematically studied. The electron-deficient nature of borophene enables activation of catalytic sites and facilitates electron transport owing to its highly conductive nature. It can act as a proton acceptor along with phosphate groups, as well as provide multiple secondary active sites in addition to Co, breaking the scaling relation of OER. For BCoPi, achieving a current density of 50 mA cm