Anisotropic Interface Successive Assembly for Bowl-Shaped Metal–Organic Framework Nanoreactors with Precisely Controllable Meso-/Microporous Nanodomains

cycloaddition, attributed to reactant accumulation within the bowl-like architecture, active site accessibility in the open mesoporous core, and improved structural stability. Overall, our study provides insights and inspiration for exploring the intricate asymmetric nanostructures of hierarchically porous MOFs with diverse potential applications.