化学
卤素
荧光
光致发光
配体(生物化学)
发光
三嗪
金属
红外光谱学
热重分析
单晶
卤化物
结晶学
无机化学
高分子化学
有机化学
材料科学
烷基
光电子学
受体
物理
生物化学
量子力学
作者
Kai Yue Zhang,Guang Zeng,Li Sun,Feng Ying Bai,Yong Heng Xing
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2019-11-14
卷期号:58 (23): 15898-15908
被引量:9
标识
DOI:10.1021/acs.inorgchem.9b02365
摘要
A series of novel metal-organic frameworks were synthesized by using semirigid ligand 1,1',1″-(1,3,5-triazine-2,4,6-triyl)tripiperidine-4-carboxylic acid (H3TTPCA) and lead halide (Cl, Br, or I). The three complexes were characterized by elemental analysis, infrared spectroscopy, ultraviolet-visible spectroscopy, powder X-ray diffraction analysis, and thermogravimetric analysis. X-ray single-crystal diffraction analysis demonstrated that all three complexes were three-dimensional inorganic-organic framework structures with Pb-X2 (X = Cl, Br, or I). However, slight differences in the chemical environment were the focus of the coordinated halogen atoms and the different compositions of metal oxygen clusters: [Pb7(COO)12Cl2], [Pb7(COO)12Br2], and [Pb7(COO)12I2]. Because of the fluorescence of the organic ligand, the three complexes showed similar photoluminescence properties at room temperature, but the intensity of emissions decreased gradually with an increase in the atomic radius of coordinated halogen atoms. Interestingly, in the fluorescence response tests, complexes 1 and 2 displayed an optical signal of fluorescence "turn-on" while complex 3 showed an optical signal of fluorescence "turn-off". Here we aim to provide a possible mechanism to explain these unique and contradictory luminescence results.
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