Recyclable Ni 3 S 4 Nanocatalyst for Hydrogenation of Nitroarenes

Abstract The synthesis of surface‐clean nanoparticles of Ni 3 S 4 , which is a rare phase of nickel sulphides, is described. Nanoparticles were synthesized in a single step via hexamethyldisilazane (HMDS) –assisted method using NiCl 2 and thiourea as starting materials. This synthetic method yielded phase pure, spherical Ni 3 S 4 nanoparticles of mean size 17 ± 4 nm having clean surfaces. The nanoparticles were characterized thoroughly by data obtained from Powder X‐ray diffraction (PXRD), Fourier‐transform infrared spectra (FT‐IR), Energy dispersive X‐ray analysis (EDAX) and Transmission electron microscopy (TEM) analyses. Since newly produced Ni 3 S 4 nanoparticles in our reaction had exposed surfaces, the catalytic behaviour of these particles was assessed by using it as a catalyst in the reduction reaction of aromatic nitro groups. We have demonstrated Ni 3 S 4 nanoparticle as a versatile catalyst for the nitro hydrogenation of both activated and deactivated nitrobenzenes using hydrazine as a hydrogen source to yield corresponding amines in high yield (∼90 %). The heterogeneous catalyst, Ni 3 S 4 nanoparticles was recycled more than ten times without any change in its activity. We have ascribed the enhanced catalytic activity of these Ni 3 S 4 nanoparticles to their clean surfaces without any surfactant molecules around them.