锐钛矿
材料科学
阳极
电化学
钠离子电池
氧气
钠
化学工程
兴奋剂
碳纤维
纳米技术
法拉第效率
无机化学
电极
光电子学
化学
复合数
催化作用
物理化学
复合材料
光催化
有机化学
工程类
冶金
作者
Qingmeng Gan,Hanna He,Kuangmin Zhao,Zhen He,Suqin Liu,Sen Yang
标识
DOI:10.1021/acsami.7b13760
摘要
The incorporation of oxygen vacancies in anatase TiO2 has been studied as a promising way to accelerate the transport of electrons and Na+ ions, which is important for achieving excellent electrochemical properties for anatase TiO2. However, wittingly introducing oxygen vacancies in anatase TiO2 for sodium-ion anodes by a facile and effective method is still a challenge. In this work, we report an innovative method to introduce oxygen vacancies into the urchin-like N-doped carbon coated anatase TiO2 (NC-DTO) by a facile plasma treatment. The superiorities of the oxygen vacancies combined with the conductive N-doped carbon coating enable the obtained NC-DTO of greatly improved sodium storage performance. When served as the anode for sodium-ion batteries, the NC-DTO electrode shows superior electrochemical performance (capacity: 272 mA h g–1 at 0.25 C, capacity retention: 98.8% after 5000 cycles at 10 C, as well as ultrahigh capacity: 150 mA h g–1 at 15 C). Density functional theory calculations combined with experimental results suggest that considerably improved sodium storage performance of NC-DTO is due to the enhanced electronic conductivity from the N-doped carbon layer as well as narrowed band gap and lowered sodiation energy barrier from the introduction of oxygen vacancies. This work highlights that introducing oxygen vacancies into TiO2 by plasma is a promising method to enhance the electrochemical property of TiO2, which also can be applied to different metal oxides for energy storage devices.
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