覆盖层
化学
催化作用
纳米颗粒
氧化还原
吸附
氧化物
多相催化
金属
氧气
水溶液
化学工程
无机化学
纳米技术
物理化学
有机化学
材料科学
工程类
作者
Jian Zhang,Hai Wang,Liang Wang,Sajjad Ali,Chengtao Wang,Qianqian Wang,Xiangju Meng,Bo Li,Dang Sheng Su,Feng‐Shou Xiao
摘要
Classical strong metal–support interactions (SMSI), which play a crucial role in the preparation of supported metal nanoparticle catalysts, is one of the most important concepts in heterogeneous catalysis. The conventional wisdom for construction of classical SMSI involves in redox treatments at high-temperatures by molecular oxygen or hydrogen, sometimes causing sintered metal nanoparticles before SMSI formation. Herein, we report that the aforementioned issue can be effectively avoided by a wet-chemistry methodology. As a typical example, we demonstrate a new concept of wet-chemistry SMSI (wcSMSI) that can be constructed on titania-supported Au nanoparticles (Au/TiO2-wcSMSI), where the key is to employ a redox interaction between Auδ+ and Ti3+ precursors in aqueous solution. The wcSMSI is evidenced by covering Au nanoparticles with the TiOx overlayer, electronic interaction between Au and TiO2, and suppression of CO adsorption on Au nanoparticles. Owing to the wcSMSI, the Au–TiOx interface with an improved redox property is favorable for oxygen activation, accelerating CO oxidation. In addition, the oxide overlayer efficiently stabilizes the Au nanoparticles, achieving sinter-resistant Au/TiO2-wcSMSI catalyst in CO oxidation.
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