多金属氧酸盐
阳离子聚合
超分子化学
胶体
自组装
肺表面活性物质
材料科学
纳米技术
聚合物
化学工程
结晶学
化学物理
化学
高分子化学
晶体结构
催化作用
有机化学
工程类
复合材料
作者
Sebastian Polarz,Bernd M. Smarsly,Markus Antonietti
出处
期刊:ChemPhysChem
[Wiley]
日期:2001-07-16
卷期号:2 (7): 457-461
被引量:131
标识
DOI:10.1002/1439-7641(20010716)2:7<457::aid-cphc457>3.0.co;2-
摘要
Increased hydrophobicity of well-defined polyoxometalate clusters is possible through complexation with cationic surfactants in a one-pot reaction. The clusters, of toroid and spherical shape and colloidal dimensions, then organized into ordered, supramolecular assemblies, as shown schematically, are similar to classical liquid crystals. The increased solubility in organic media opens the door to new polyoxometalate-polymer hybrid materials.
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