催化作用
炭黑
三聚氰胺
拉曼光谱
循环伏安法
旋转圆盘电极
化学
电化学
碳纤维
X射线光电子能谱
无机化学
氧还原反应
原位
核化学
材料科学
电极
化学工程
有机化学
物理化学
天然橡胶
复合材料
复合数
工程类
物理
光学
作者
Hong Zhu,Li Ke,Nanjun Chen,Fanghui Wang
标识
DOI:10.1016/j.ijhydene.2017.08.179
摘要
Enhancing the activity and stability of the non-precious metal catalyst (NPMC) for oxygen reduction reaction (ORR) is vital for the commercialization of fuel cells. Herein, we put forward a method in which the melamine formaldehyderesin was used as a precursor to encapsulate in situ Co2O3 into carbon black to form Co2O3@MF-C catalysts. The prepared catalysts were characterized by TEM, XRD, XPS, BET, and Raman spectroscopy. The electrocatalytic activity was measured by using rotating disk electrode (RDE) voltammetry. The Co2O3@MF-Cs shows outstanding electrocatalytic activity in alkaline solution compared with the commercial Pt/C catalyst. The 20%Co2O3@MF-C-650 shows the highest activity for ORR and its initial reduction potential and half-wave potential reach 1.01 V and 0.94 V, respectively, in 0.1 M KOH solution. The prepared catalysts also follow the 4-electron pathway ORR process both in alkaline and in acid conditions.
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