电解
双金属片
甲烷化
氧化剂
电化学
化学工程
材料科学
析氧
金属
催化作用
化学
无机化学
电极
冶金
电解质
有机化学
物理化学
工程类
生物化学
作者
Patryk Błaszczak,M. Zając,Agata Ducka,Krzysztof Matlak,Barbara Wolanin,Sea-Fue Wang,Anna Mandziak,Beata Bochentyn,Piotr Jasiński
标识
DOI:10.1016/j.ijhydene.2022.08.057
摘要
To study the synergy between the transition metals for enhancing the electrochemical and chemical activity, a series of SOECs were modified with a small amount of Co ions, namely 1.8, 3.6, and 5.4 wt% in the reduced state. The addition of βCD into the precursor solution allowed for extremely fine dispersion of Co species across the Ni-YSZ cermet structure. The sample containing 3.6 wt% Co reached an outstanding over 2.5-times-higher concentration of CH4 in the outlet stream. At the same time, the Co greatly enhanced the electrochemical efficiency of water and CO2 co-electrolysis. Full characterization involving STXM imaging allowed for better understanding of the synergy between the Ni and Co host metal and made it possible to find the causes of the increased activity. It revealed the complexity of the substructures formed within the electrode. A novel discovery was described regarding the NiCo2O4 spinel structure subjected to the O2-TPO measurements. Despite the applied oxidizing atmosphere, the catalyst evolved oxygen at elevated temperatures in a reversible manner. The performance tests indicated the roles of both rWGS and direct electrolysis of CO2 in the electroreduction process. The addition of Co did not influence the prolonged degradation of the cell.
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