Electrolyte and Additive Engineering for Zn Anode Interfacial Regulation in Aqueous Zinc Batteries

Abstract Aqueous Zn‐metal batteries (AZMBs) have gained great interest due to their low cost, eco‐friendliness, and inherent safety, which serve as a promising complement to the existing metal‐based batteries, e.g., lithium‐metal batteries and sodium‐metal batteries. Although the utilization of aqueous electrolytes and Zn metal anode in AZMBs ensures their improved safety over other metal batteries meanwhile guaranteeing their decent energy density at the cell level, plenty of challenges involved with metallic Zn anode still await to be addressed, including dendrite growth, hydrogen evolution reaction, and zinc corrosion and passivation. In the past years, several attempts have been adopted to address these problems, among which engineering the aqueous electrolytes and additives is regarded as a facile and promising approach. In this review, a comprehensive summary of aqueous electrolytes and electrolyte additives will be given based on the recent literature, aiming at providing a fundamental understanding of the challenges associated with the metallic Zn anode in aqueous electrolytes, meanwhile offering a guideline for the electrolytes and additives engineering strategies toward stable AZMBs in the future.