镍
对偶(语法数字)
组合化学
光催化
催化作用
化学
催化循环
杂原子
纳米技术
材料科学
戒指(化学)
光催化
有机化学
文学类
艺术
作者
Shorouk O. Badir,Gary A. Molander
出处
期刊:Chem
[Elsevier]
日期:2020-06-01
卷期号:6 (6): 1327-1339
被引量:169
标识
DOI:10.1016/j.chempr.2020.05.013
摘要
Progress in Ni/photoredox dual catalysis has enabled the construction of C(sp3)-hybridized centers under extremely mild reaction conditions in the presence of diverse functional groups. These strategies, however, are mainly restricted to the assembly of one C–C or C–heteroatom linkage because of the competitive two-component reactions and facile β-hydride elimination from alkylmetal complexes. Recently, photoinduced nickel-catalyzed 1,2-difunctionalizations of alkenes and alkynes have attracted extensive research efforts because they allow the construction of two sequential chemical bonds from inexpensive starting materials in one pot. Herein, we explore recent advances, state the current challenges, and discuss perspectives on the design of new catalytic systems.
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