Experimental Studies of Reboiler Heat Duty for CO2 Desorption from Triethylenetetramine (TETA) and Triethylenetetramine (TETA) + N-Methyldiethanolamine (MDEA)

作者
Xiao Luo,Kaiyun Fu,Zhen Yang,Hongxia Gao,Wichitpan Rongwong,Zhiwu Liang,Paitoon Tontiwachwuthikul
出处
期刊:Industrial & Engineering Chemistry Research [American Chemical Society]
卷期号:54 (34): 8554-8560 被引量:32
标识
DOI:10.1021/acs.iecr.5b00158
摘要

Amine scrubbing is regarded as one of the most suitable technologies for postcombustion CO 2 capture. However, data on regeneration energy and performance is limited in literature. In this study, the reboiler heat duties of triethylenetetramine (TETA) and triethylenetetramine (TETA) + N -methyldiethanolamine (MDEA) were experimentally evaluated in a bench-scale stripper packed with Dixon ring random packing. The effects of various operating parameters on the desorption performance (presented in terms of reboiler heat duty, Q reboiler ) were investigated, including lean loading, rich loading, amine concentration, solvent flow rate, and amine type. The experimental results showed that the Q reboiler was very sensitive to these process parameters. In addition, a comparison of the Q reboiler of TETA, monoethanolamine (MEA), and diethylenetriamine (DETA) was conducted to evaluate the potential for TETA’s application in the CO 2 capture process. The results obtained in this work showed that the Q reboiler of TETA, as a function of amount of CO 2 released, is lower than that of MEA and DETA.

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