氰基乙酸
咔唑
发色团
光化学
接受者
能量转换效率
噻吩
摩尔吸收率
材料科学
色素敏化染料
吸收(声学)
罗丹宁
化学
有机化学
光电子学
物理化学
光学
电极
电解质
物理
复合材料
凝聚态物理
作者
Han Li,Xiaoyan Zu,Yanhong Cui,Huabiao Wu,Qing Ye,Jianrong Gao
标识
DOI:10.1016/j.orgel.2014.04.016
摘要
New D–A–π–A carbazole dyes containing benzothiadiazole chromophores were designed and synthesized for application in dye-sensitized solar cells (DSSCs). The light-harvesting capabilities and photovoltaic performance of these dyes were investigated systematically through comparison of different π-bridges and acceptors. Compared with thiophene bridge, benzene bridge provides improved IPCE and VOC, which leads to better photoelectricity conversion efficiency. Dyes with cyanoacetic acid acceptor display superior photovoltaic properties though with shorter absorption maximum and lower molar absorption coefficient compared with dyes with rhodanine acetic acid acceptor. Therefore, dye with benzene bridge and cyanoacetic acid acceptor shows the most efficient photoelectricity conversion efficiency and has the maximum η value of 5.40% (VOC = 710 mV, JSC = 10.99 mA/cm2, and ff = 0.71) under simulated AM 1.5 irradiation (100 mW/cm2).
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