化学
硼氢化
烯丙基重排
催化作用
有机化学
组合化学
作者
M. Satoh,Yoshihiro Nomoto,Norio Miyaura,Akira Suzuki
标识
DOI:10.1016/s0040-4039(01)80656-0
摘要
Hydroboration of 1,3-butadiene, isoprene, myrcene, 2,3-dimethyl-1,3-butadiene, and 1,3-cyclohexadiene with catecholborane (1,3,2-benzodioxaborole) in the presence of Pd(PPh3)4 or Rh4(CO)12 catalysts proceeds smoothly to provide 2-[(Z)-2-alkyl-2-butenyl]-1,3,2-benzodioxaboroles in very high regio- and stereoselectivity.
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