Two‐step consecutive reaction model and kinetic parameters relevant to the decomposition of Chinese forest fuels

Abstract Decomposition of some Chinese forest fuels has been studied by means of nonisothermal thermogravimetric analysis in oxidative and inert atmosphere at low heating rates. A comparison between thermogravimetric curves obtained in air and nitrogen shows that the existence of oxygen enhances the decomposition rate and changes the mechanisms of thermal degradation. After the water evaporation, two well‐defined decomposition stages have been observed in thermogravimetric curves obtained in air, which correspond to oxidative degradation of main components and oxidation of char formed. A kinetic model named “two‐step consecutive reaction model” is developed to describe the thermal degradation process of these materials in air, and there is a good agreement between the experimental and calculated thermogravimetric and derivative thermogravimetric curves. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 571–576, 2006