化学
超分子化学
亚胺
缩合反应
晶体工程
冷凝
块(置换群论)
组合化学
晶体结构
有机化学
催化作用
几何学
数学
热力学
物理
作者
Tom Kunde,Tobias Pausch,Guido J. Reiß,Bernd Schmidt
出处
期刊:Synlett
[Georg Thieme Verlag KG]
日期:2021-03-30
卷期号:33 (02): 161-165
被引量:11
摘要
Abstract A novel highly fluorinated dialdehyde was prepared by a two-stage synthesis. This reactive building block for dynamic imine chemistry was used in a condensation reaction to generate the first extensively fluorinated trianglimine. An analysis of the material properties and, especially, the crystal structure of the [3+3] macrocycle revealed a supramolecular organic framework with tubular porous channels. The use of fluorinated ligands to generate hydrophobic electron-deficient channel-like pores is an important addition to the ever-expanding field of supramolecular networks and to trianglimine chemistry in general.
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