A highly efficient metal-free protocol for the synthesis of linear polydicyclopentadiene
嬉戏
复分解
化学
聚合
有机化学
聚合物
作者
Xuejin Yang,Laura Murphy,Farihah M. Haque,Scott M. Grayson,Andrew J. Boydston
出处
期刊:Polymer Chemistry [The Royal Society of Chemistry] 日期:2021-01-01卷期号:12 (19): 2860-2867被引量:6
标识
DOI:10.1039/d1py00191d
摘要
We have developed a highly efficient synthesis of linear polydicyclopentadiene (pDCPD) via photoredox mediated metal-free ring-opening metathesis polymerization (MF-ROMP) and investigated the Tg–Mn dependence of linear pDCPD.