环境化学
化学
硝酸盐
气溶胶
波动性(金融)
环境科学
有机化学
金融经济学
经济
作者
Penggang Zheng,Yi Chen,Zhe Wang,Yuliang Liu,Wei Pu,Chuan Yu,Men Xia,Yang Xu,Jia Guo,Yishuo Guo,Linhui Tian,Xiaohui Qiao,Dandan Huang,Chao Yan,Wei Nie,Douglas R. Worsnop,Shuncheng Lee,Tao Wang
标识
DOI:10.1021/acs.est.2c09252
摘要
Oxygenated organic molecules (OOMs) are critical intermediates linking volatile organic compound oxidation and secondary organic aerosol (SOA) formation. Yet, the understanding of OOM components, formation mechanism, and impacts are still limited, especially for urbanized regions with a cocktail of anthropogenic emissions. Herein, ambient measurements of OOMs were conducted at a regional background site in South China in 2018. The molecular characteristics of OOMs revealed dominant nitrogen-containing products, and the influences of different factors on OOM composition and oxidation state were elucidated. Positive matrix factorization analysis resolved the complex OOM species to factors featured with fingerprint species from different oxidation pathways. A new method was developed to identify the key functional groups of OOMs, which successfully classified the majority species into carbonyls (8%), hydroperoxides (7%), nitrates (17%), peroxyl nitrates (10%), dinitrates (13%), aromatic ring-retaining species (6%), and terpenes (7%). The volatility estimation of OOMs was improved based on their identified functional groups and was used to simulate the aerosol growth process contributed by the condensation of those low-volatile OOMs. The results demonstrate the predominant role of OOMs in contributing sub-100 nm particle growth and SOA formation and highlight the importance of dinitrates and anthropogenic products from multistep oxidation.
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