电致发光
发光二极管
材料科学
钙钛矿(结构)
卤化物
纳米晶
光电子学
二极管
聚合物
发光
纳米技术
化学
结晶学
无机化学
复合材料
图层(电子)
作者
Benzheng Lyu,Hong Lin,Dongyu Li,А. А. Сергеев,Qiang Wang,Zhengyan Jiang,Lijun Huo,Haibin Su,Kam Sing Wong,Yufeng Wang,Wallace C. H. Choy
出处
期刊:ACS energy letters
[American Chemical Society]
日期:2024-04-12
卷期号:: 2118-2127
标识
DOI:10.1021/acsenergylett.4c00355
摘要
Mixed-halide perovskite nanocrystals (PeNCs) featuring bandgap-tunable luminescence with narrow bandwidth have emerged as promising electroluminescent materials for light-emitting diodes (LEDs) to satisfy the color standard of Rec. 2100. However, the phase segregation of mixed-halide perovskites severely restricts the spectral stability and lifetime of perovskite LEDs (PeLEDs). Here, we report that the introduction of multifunctional side-chain-promoted polymer architectures in the synthesis of I/Br-mixed PeNCs to suppress halide segregation and enable electroluminescent stability of the PeLEDs up to ∼2500 min, which is the longest to our knowledge. Meanwhile, the PeLEDs exhibit the pure-red electroluminescence spectrum with Commission Internationale de l'Eclairage coordinates (0.705, 0.292) at one of the highest external quantum efficiencies reported to date, 23.6%. Fundamentally, the as-proposed polymer ligand architecture simultaneously offers long-term nanocrystal dispersion, good charge transport, defect elimination, and phase segregation suppression. Overall, the work demonstrates the potential of the multifunctionalized polymer ligands for developing high-performance PeLEDs toward practical applications.
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