Coagulation performance and mechanism of different hydrolyzed aluminum species for the removal of composite pollutants of polyethylene and humic acid

Microplastics (MPs) and natural organic matter (NOM) composite pollutants have become emerging contaminants with potential threats. Coagulation has been widely used to remove MPs and NOM, but the underlying mechanisms for the removal of MPs-NOM composite pollutants by hydrolyzed Al species remain unclear. Therefore, the coagulation performance and mechanism of AlCl3, polyaluminum chloride with basicity of 2.2 (PAC22), and PAC25 in treating polyethylene (PE), humic acid (HA), and PE-HA composite systems were systematically investigated. The results showed that in the single PE system, PAC25 with hexagonal clusters achieved the maximum removal (68.09%) (pH: 5, dosage: 0.5 mM) since adsorption bridging and sweeping effect were the main mechanisms for PE removal. The adsorption of HA on the PE surface enhanced its hydrophilicity and electrostatic repulsion, resulting in decreased PE removal. In the AlCl3-PE-HA system, the oligomeric Al first interacted with the -COOH and C-OH of HA through complexation, followed by the meso- and polymers of Al interacted with PE by electrostatic adsorption. The pre-formed medium polymeric Al species (Alb) and colloidal or solid Al species (Alc) in PAC22 and PAC25 formed complexes with the -OH and -COOH groups of HA, respectively, and then removed PE by adsorption bridging and sweeping effect. Microplastics (MPs), as an emerging pollutant, can pose a threat to ecosystems and human health. And the environmental hazards of the composite contaminants formed by MPs and humic acid (HA) cannot be ignored as well. Aluminum (Al) salt coagulants are expected to be effective in the removal of MPs and MPs-HA. Elucidating the coagulation mechanism of MPs and MPs-HA by hydrolyzed Al species can provide theoretical guidance for the efficient removal of MPs-HA composite pollutants in actual water bodies.