化学
阳离子聚合
水溶液
对映选择合成
铵
主客化学
水溶性
杯芳烃
组合化学
有机化学
寄主（生物学）
高分子化学
分子
超分子化学
催化作用
生物
生态学
作者
Kotoko Nakagawa,Kanaru Akimoto,Bunta Nakayasu,Saki Nagashima,Mamoru Tobisu,Michael P. Schramm,Shinobu Aoyagi,Toru Amaya
出处
期刊：Organic Letters
[American Chemical Society]
日期：2023-08-04
卷期号：25 (32): 5969-5973
被引量：7
标识
DOI：10.1021/acs.orglett.3c02074
摘要
Synthesis and host-guest chemistry of water-soluble (pH 12.5) chiral spirobifluorene-based macrocycles 2-[n] were carried out. Cationic guests, such as quaternary ammonium salts, were accommodated well in the hosts. Cp2Co+ was especially strongly bound in 2-[4] (Ka of up to 3.0 × 105 M-1). Enantioselective recognition with (l)-carnitine was also achieved.
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