A liquid metal/carbon nanotubes complex enabling ultra-fast polymerization of super-robust, stretchable adhesive hydrogels for highly sensitive sensor

Carbon nanotubes (CNTs) usually served as conductive and reinforcing nanofillers for making nanocomposites have never been reported to play a role in accelerating fabrication of hydrogels. Herein, we report an important discovery that by involving CNTs and liquid metal (LM) to form a complex (LM@CNTs), multifunctional hydrogels are rapidly prepared from vinyl monomers without heating or adding any initiators and crosslinkers. Study results demonstrate that LM@CNTs not only performs as both initiator and crosslinker for synthesizing hydrogels, but also dramatically reduces the polymerization duration from 3 days to minute levels, compared with that of only LM involved in hydrogel fabrication. Specifically, the complex initiates (<60 s) and crosslinks (<8min) monomers to form the high-performance hydrogels, which significantly reduces energy consumptions. The resulting polyacrylic acid (PAA) hydrogel possesses super stretchability (∼1200 %), high tensile strength (0.96 MPa), outstanding strain sensitivity (Gauge factor = 15.40 at 300–500 % strain), and excellent adhesion to various substrate surfaces. Additionally, the injectable molding performance will benefit the mass production of the hydrogels, which exhibits great potential for applications of wearable flexible sensors. This study provides an environmentally friendly, rapid polymerization, and energy-saving strategy by effectively applying nano-fillers for viable fabrication and application of multifunctional hydrogels.