Nitrogen and magnesium codoped biochar activates periodate to remediate bensulfuron methyl-contaminated water at low temperature: Performance, mechanisms, and phytotoxicity

Bensulfuron methyl (BSM), a typical sulfonylurea herbicide, has been widely used worldwide for weed suppression and crop protection. Nevertheless, the long-term and prolonged usage led to residues in environment, resulting in the reduction of crop yields and even threatening food security. In this study, the nitrogen/magnesium codoped biochar (NMg-BC) was prepared via two-step pyrolysis method to activate periodate (PI) for BSM degradation. The results demonstrated BSM degradation rate was 87.9 % within 10 min by NMg-BC/PI system at 15 ℃. The system exhibited the favorable tolerance to environmental changes (pH, temperature, anions, and humic acids), presenting high removal efficiency of BSM. Radicals (IO