材料科学
沸石咪唑盐骨架
纳米复合材料
微波食品加热
电场
咪唑酯
吸收(声学)
纳米技术
光电子学
化学工程
复合材料
吸附
金属有机骨架
有机化学
化学
物理
量子力学
工程类
作者
Zhenguo Gao,Aamir Iqbal,Tufail Hassan,Shengchong Hui,Hongjing Wu,Chong Min Koo
标识
DOI:10.1002/adma.202311411
摘要
Abstract The use of heterointerface engineering, which can play a pivotal role in producing advanced microwave‐absorbing materials, to prepare a zeolitic imidazolate framework (ZIF)–MXene nanocomposite is reported herein. The ZIF–MXene composites can be prepared by electrostatic self‐assembly of negatively charged titanium carbide MXene flakes and positively charged Co‐containing ZIF nanomaterials. This approach effectively creates abundant Mott–Schottky heterointerfaces exhibiting a robust built‐in electric field (BIEF) effect, as evidenced by experimental and theoretical analyses, leading to a notable attenuation of electromagnetic energy. Systematic manipulation of the BIEF‐exhibiting heterointerface, achieved through topological modulation of the ZIF, proficiently alters charge separation, facilitates electron migration, and ultimately enhances polarization relaxation loss, resulting in exceptional electromagnetic wave absorption performance (reflection loss RL min = −47.35 dB and effective absorption bandwidth f E = 6.32 GHz). The present study demonstrates an innovative model system for elucidating the interfacial polarization mechanisms and pioneers a novel approach to developing functional materials with electromagnetic characteristics through spatial charge engineering. This article is protected by copyright. All rights reserved
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