材料科学
金属有机骨架
计算机科学
环境科学
化学
有机化学
吸附
作者
Shing Bo Peh,Avishek Karmakar,Dan Zhao
标识
DOI:10.1016/j.trechm.2019.10.007
摘要
Flexible materials can adapt to external stimuli with predictable and controllable responses. The emergence of dynamic behavior in metal–organic frameworks (MOFs) is promising for the development of ‘smart’ materials for applications that leverage their porosities and tunable chemical compositions, including the storage, separation, and sensing of small molecules. The translation of molecular structural transformations to macroscopic responses requires the multiscale design of flexible MOF systems. This review summarizes the progress in this area focusing on the past 3–5 years, starting from the modular assembly of building blocks and continuing to the management of dynamics in device architectures.
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