溶解度
聚合物
成核
热力学
聚苯乙烯
溶解度参数
材料科学
色散(光学)
相(物质)
伦敦分散部队
化学
物理化学
有机化学
分子
物理
复合材料
光学
范德瓦尔斯力
作者
Linyan Wang,Hongfu Zhou,Xiangdong Wang,Jianguo Mi
标识
DOI:10.1021/acs.iecr.5b04343
摘要
A classical density functional theory approach has been applied to evaluate the solubility and interfacial properties of CO2 dissolved in poly(methyl methacrylate) (PMMA) and polystyrene (PS) matrices quantitatively. Apart from the free-energy functional for hard-sphere reference given by the fundamental measure theory, a weighted free-energy functional for attractive dispersion and the contributions of chain connectivity and conformation have been integrated into the theoretical model to improve its predictive capability. The force-field parameters are cited from the literature, except that the Lennard-Jones potentials of sites are regressed to reproduce the experimental gas–liquid phase equilibria of pure PMMA and PS. It is shown that, in the two systems, the current model provides reliable predictive results of solubilities, swelling ratios, and interfacial tensions, which are particularly important in the bubble nucleation during polymer foaming.
科研通智能强力驱动
Strongly Powered by AbleSci AI