Synthesis and controllable self-assembly of 3D amphiphilic organoplatinum( ii ) metallacages in water

A 3D amphiphilic supramolecular coordination metallacycle M1 was designed and fabricated using a new method called “coordination driven self-assembly”. It can self-assemble into well-defined vesicles and further assemble into nanofibres and hybrid vesicles. Importantly, the hybrid vesicles can be applied in photocatalysis in water.