Convincing Synthesis of Atomically Thin, Single-Crystalline InVO4 Sheets toward Promoting Highly Selective and Efficient Solar Conversion of CO2 into CO

Atomically thin, single-crystalline InVO₄ sheets with the uniform thickness of ∼1.5 nm were convincingly synthesized, which was identified with strong, low-angle X-ray diffraction peaks. The InVO₄ atomic layer corresponding to 3 unit cells along [110] orientation exhibits highly selective and efficient photocatalytic conversion of CO₂ into CO in the presence of water vapor. Surface potential change measurement and liquid photoluminescence decay spectra confirm that the atomically ultrathin structure can shorten the transfer distance of charge carriers from the interior onto the surface and decrease the recombination in body. It thus allows more electrons to survive and accumulate on the surface, which is beneficial for activation and reduction of CO₂. In addition, exclusively exposed {110} facet of the InVO₄ atomic layer was found to bind the generating CO weakly, facilitating quick desorption from the catalyst surface to form free CO molecules, which provides an ideal platform to catalytically selective CO product.