In Situ Growth of Ni2P–Cu3P Bimetallic Phosphide with Bicontinuous Structure on Self-Supported NiCuC Substrate as an Efficient Hydrogen Evolution Reaction Electrocatalyst

A direct and effective approach is proposed to fabricate bimetallic phosphide Ni₂P–Cu₃P with controllable phase compn. and distribution for catalytic hydrogen evolution reaction (HER). Unlike previously reported precursors, a porous Ni-Cu alloy incorporated with graphitic carbon (NiCuC) prepd. via powder metallurgy is employed herein, and the generated Ni₂P–Cu₃P@NiCuC possesses a hierarchical porous structure and controllable phase compn. due to the high porosity and tunable Ni/Cu ratio of the precursor. With an optimal Cu content of 30.0 wt. %, the catalyst demonstrates the highest catalytic activity due to a synergistic interaction between different metallic phosphide sites and the facilitated mass transport. Meanwhile, d. functional theory (DFT) calcn. reveals that the at. interaction of Ni₂P–Cu₃P substantially lower the activation barrier for enhanced HER catalytic activity. Finally, the powder metallurgy provides an approach for the design of bimetallic phosphide electrocatalysts for HER and other catalytic applications.