Ball milling sulfur-doped nano zero-valent iron @biochar composite for the efficient removal of phosphorus from water: Performance and mechanisms

This study successfully prepared a novel sulfur-doped nano zero-valent iron @biochar (BM-SnZVI@BC) by modifying corn stover biochar with Fe0 and S0 using a mechanical ball milling method for effective phosphorus (P) adsorption in the waterbody. Batch experiments revealed that BM-SnZVI@BC (BC/S0/Fe0 = 3:1:1) reached a Qmax of 25.00 mg P/g and followed PFO and Langmuir models. This work had shown that electrostatic attraction, surface chemical precipitation, hydrogen bonding, and ligand effects all contributed to P removal. Since the FeS layer mitigated the oxidation-induced surface passivation of nZVI, sulfidation significantly extended the lifetime of BM-SnZVI@BC, removing 84.4% of P even after 60 d aging in air. The regeneration experiments of composites showed that re-ball milling destroyed the surface iron oxide layer to improve the properties of the recovered material. This is an essential step in the design of P-removal agents to implement anti-aging and commercialization of adsorbents for engineering applications.