丙烯酸
蒸馏水
高岭石
肿胀 的
热重分析
热稳定性
材料科学
高吸水性高分子
复合数
核化学
傅里叶变换红外光谱
高分子化学
膨胀能力
化学工程
聚合
化学
复合材料
有机化学
聚合物
色谱法
共聚物
冶金
工程类
作者
Wenxu Zhang,Lulu Guo,Qian Liu,Mei Yang,Jing Chen,Ziqiang Lei
摘要
Abstract The protein‐based superabsorbent composite FCP‐g‐PAA/Kaolinite is prepared by grafting acrylic acid (AA) into the flax cake protein (FCP) using free radical polymerization in this study. The chemical structure, thermal stability, and the morphology of the FCP‐g‐PAA/Kaolinite are characterized by Fourier transform infrared, Thermogravimetric analysis, and scanning electron microscope. The results show that AA was grafted successfully into FCP. And, it has the maximum swelling capacity where the MBA concentration, APS concentration, Kaolinite concentration, FCP concentration, neutralization degree, and reaction time was 0.13%, 1.4%, 8%, 9%, 70% and 2 h, respectively. The swelling capacity reaches 860 g/g in distilled water, 238 g/g in tap water and 78 g/g in 0.9% NaCl. In addition, its water absorbency can still reach 60% after reuse for six times and the water retention rate of the material was 70% after 12 h. Therefore, FCP has a broad application prospect as a material for preparing superabsorbent composite.
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